Mohs scale of mineral hardness

The Mohs scale of mineral hardness (/mz/) is a qualitative ordinal scale characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. Created in 1822 by German geologist and mineralogist Friedrich Mohs, it is one of several definitions of hardness in materials science, some of which are more quantitative.[1][2]

Open wooden box with ten compartments, each containing a numbered mineral specimen.
Mohs hardness kit, containing one specimen of each mineral on the ten-point hardness scale

The method of comparing hardness by observing which minerals can scratch others is of great antiquity, having been mentioned by Theophrastus in his treatise On Stonesc.  300 BC, followed by Pliny the Elder in his Naturalis Historiac.  AD 77.[3][4][5] While greatly facilitating the identification of minerals in the field, the Mohs scale does not show how well hard materials perform in an industrial setting.[6]

UsageEdit

Despite its lack of precision, the Mohs scale is relevant for field geologists, who use the scale to roughly identify minerals using scratch kits. The Mohs scale hardness of minerals can be commonly found in reference sheets.

Mohs hardness is useful in milling. It allows assessment of which kind of mill will best reduce a given product whose hardness is known.[7] The scale is used at electronic manufacturers for testing the resilience of flat panel display components (such as cover glass for LCDs or encapsulation for OLEDs).

The Mohs scale has been used to evaluate the hardness of smartphone screens. Most modern smartphone displays use Gorilla Glass that scratches at level 6 with deeper grooves at level 7 on the Mohs scale of hardness.[8]

MineralsEdit

The Mohs scale of mineral hardness is based on the ability of one natural sample of mineral to scratch another mineral visibly. The samples of matter used by Mohs are all different minerals. Minerals are chemically pure solids found in nature. Rocks are made up of one or more minerals. As the hardest known naturally occurring substance when the scale was designed, diamonds are at the top of the scale. The hardness of a material is measured against the scale by finding the hardest material that the given material can scratch, or the softest material that can scratch the given material. For example, if some material is scratched by apatite but not by fluorite, its hardness on the Mohs scale would fall between 4 and 5.[9]

"Scratching" a material for the purposes of the Mohs scale means creating non-elastic dislocations visible to the naked eye. Frequently, materials that are lower on the Mohs scale can create microscopic, non-elastic dislocations on materials that have a higher Mohs number. While these microscopic dislocations are permanent and sometimes detrimental to the harder material's structural integrity, they are not considered "scratches" for the determination of a Mohs scale number.[10]

The Mohs scale is a purely ordinal scale. For example, corundum (9) is twice as hard as topaz (8), but diamond (10) is four times as hard as corundum. The table below shows the comparison with the absolute hardness measured by a sclerometer, with pictorial examples.[11][12]

Mohs hardnessMineralChemical formulaAbsolute hardness[13]Image
1TalcMg3Si4O10(OH)21 
2GypsumCaSO4·2H2O2 
3CalciteCaCO314 
4FluoriteCaF221 
5ApatiteCa5(PO4)3(OH,Cl,F)48 
6Orthoclase feldsparKAlSi3O872 
7QuartzSiO2100 
8TopazAl2SiO4(OH,F)2200 
9CorundumAl2O3400 
10DiamondC1500 

On the Mohs scale, a streak plate (unglazed porcelain) has a hardness of approximately 7.0. Using these ordinary materials of known hardness can be a simple way to approximate the position of a mineral on the scale.[14]

Intermediate hardnessEdit

The table below incorporates additional substances that may fall between levels:[15]

HardnessSubstance or mineral
0.2–0.3caesiumrubidium
0.5–0.6lithiumsodiumpotassium, candle wax
1talc
1.5galliumstrontiumindiumtinbariumthalliumleadgraphiteice[16]
2hexagonal boron nitride,[17] calciumseleniumcadmiumsulfurtelluriumbismuthgypsum
2–2.5halite (rock salt), fingernail[18]
2.5–3goldsilveraluminiumzinclanthanumceriumjet
3calcitecopperarsenicantimonythoriumdentin
3.5platinum
4fluoriteironnickel
4–4.5ordinary steel
5apatite (tooth enamel), zirconiumpalladiumobsidian (volcanic glass)
5.5berylliummolybdenumhafniumglasscobalt
6orthoclasetitaniummanganesegermaniumniobiumuranium
6–7fused quartziron pyritesiliconrutheniumiridiumtantalumopalperidottanzaniterhodiumjade
7osmiumquartzrheniumvanadium
7.5–8emeraldberylzircontungstenspinel
8topazcubic zirconiahardened steel
8.5chrysoberylchromiumsilicon nitridetantalum carbide
9corundum (includes sapphire and ruby), tungsten carbidetitanium nitride
9–9.5silicon carbide (carborundum), tantalum carbidezirconium carbidealuminaberyllium carbidetitanium carbidealuminum borideboron carbide.[note 1][19][20]
9.5–near 10boronboron nitriderhenium diboride (a-axis),[21] stishovitetitanium diboridemoissanite (crystal form of silicon carbide)
10diamondcarbonado

Comparison with Vickers scaleEdit

Comparison between Mohs hardness and Vickers hardness:[22]

Mineral
name
Hardness (Mohs)Hardness (Vickers)
(kg/mm2)
Graphite1–2VHN10 = 7–11
Tin1.5VHN10 = 7–9
Bismuth2–2.5VHN100 = 16–18
Gold2.5VHN10 = 30–34
Silver2.5VHN100 = 61–65
Chalcocite2.5–3VHN100 = 84–87
Copper2.5–3VHN100 = 77–99
Galena2.5VHN100 = 79–104
Sphalerite3.5–4VHN100 = 208–224
Heazlewoodite4VHN100 = 230–254
Carrollite4.5–5.5VHN100 = 507–586
Goethite5–5.5VHN100 = 667
Hematite5–6VHN100 = 1,000–1,100
Chromite5.5VHN100 = 1,278–1,456
Anatase5.5–6VHN100 = 616–698
Rutile6–6.5VHN100 = 894–974
Pyrite6–6.5VHN100 = 1,505–1,520
Bowieite7VHN100 = 858–1,288
Euclase7.5VHN100 = 1,310
Chromium8.5VHN100 = 1,875–2,000


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